The reaction of triphenylarsine oxide with ethyl iodo-acetate leading to triphenyl (carboethoxy)methylarsonium triiodide

✍ Scribed by Boris E. Abalonin; Il'yas S. Nizamov; Dmitry B. Krivolapov; Il'nar D. Nizamov; Ravil N. Khaibullin; Lyubov A. Al'metkina; Elvira S. Batyeva; Igor A. Litvinov

• Publisher: John Wiley and Sons
• Year: 2004
• Tongue: English
• Weight: 76 KB
• Volume: 15
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.20050

✦ Synopsis

Abstract

New data are presented for some processes accompaning “retro‐Arbuzov” reaction of tertiary arsine oxides with halogen‐containing reagents. Triphenyl (carboethoxy)methylarsonium triiodide 10a was obtained in the reaction of triphenylarsine oxide 1a with excess of ethyl iodoacetate 2a. The structure of 10a was established by X‐ray single crystal diffraction. © 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:482–485, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20050