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The Reaction of (Trialkylsilyl)vinylketenes with Carbenoid Reagents: A New [4+1] Annulation Route to Cyclopentenones

โœ Scribed by Loebach, Jennifer L.; Bennett, Dawn M.; Danheiser, Rick L.

Book ID
127115669
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
122 KB
Volume
120
Category
Article
ISSN
0002-7863

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We have previously dercribed reactions of sulfonee with CC14-KOH-t-BuOH In which a-chloro sulfonee (and dlchlorocarbene) are Initially formed and are usually rapidly transformed In situ Into different type8 of products. 2 Thue, dibenzyl eulfone Is monochlorinated and converted Into trans-stllbene; 2