The reactivity of superoxide ion (0;)' toward biological compounds has become subject of considerable interest since the discovery that 01 is a respiratory intermediate of aerobic
The reaction of superoxide ion with vitamin K1 and its related compounds
β Scribed by Isao Saito; Toshiaki Otsuki; Teruo Matsuura
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 218 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The reaction of potassium superoxide with vitamin K, and its related compounds in the presence of crown ether gave the corresponding 2,3-oxide and nhthalic acid.
The oxidative cleavage of oxirane ring by superoxide ion has been observed with vitamin K, 2,3-oxide and certain epoxides.
π SIMILAR VOLUMES
## Abstract The kinetics of the reaction of the superoxide ion with ethyl acetate have been studied in DMF, AN, and their mixtures. It was shown that the rate constants depend on the ethyl acetate concentration, which indicates the formation of an intermediate in this process. Equilibrium constants