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The reaction of ozone with acetylenic hydrocarbons

โœ Scribed by F.J. Dillemuth S.J.; ; C.C. Schubert S.J.; ; D.R. Skidmore

Publisher
Elsevier Science
Year
1962
Tongue
English
Weight
158 KB
Volume
6
Category
Article
ISSN
0010-2180

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๐Ÿ“œ SIMILAR VOLUMES

Arrhenius constants for the reactions of
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The kinetics of ozonation of C,H, and C,H, have been studied in the gas phase from -40 to -95ยฐC (C,H,) and + I 0 to -30% (C,H,). The 0, concentrations were near M, and the hydrocarbons were present in 2-to 25-fold excess. A few experiments with propylene were also carried out. The reactions were fol

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main product. \r.hich undergoes stereoselective Diels-Alder addition with 1 ,3-dienesll1. Elucidation of the mechanism of this reaction required X-ray determination of the configuration and conformation of ( I ).

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The progressive reaction of ozone and oxygen mixtures with charcoal at 26ยฐC was studied to specified weight-gains and to different subsequent weight-losses when outgassed at various temperatures. Although each ozone-treated adsorbent gave evidence of continuous decomposition when introduced into a v