the formation of higher oxides of chlorine such as Cl 2 O 4 , Cl 2 O 6 , and Cl 2 O 7 has been observed [5 -8]. The reaction mechanisms are not understood but may involve the formation of ClO 3 which has recently been observed in an inert matrix [9]. In these systems, ClO 3 can be formed via the add
The reaction of O(3P) with propionaldehyde and acrolein in a fast-flow system
β Scribed by R.D. Cadle; San San Lin; R.F. Hausman Jr.
- Book ID
- 119020003
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 262 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0045-6535
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π SIMILAR VOLUMES
## Abstract The reaction of O(^3^__P__) atoms with propanehas been studied at temperatures near 300 K by using a discharge flow system. Oxygen atoms were generated in the absence of molecular oxygen by the reaction N + NO β N~2~ + O, nitrogen atoms having been generated in a microwave discharge. Ra
## Abstract The reaction of O(^3^__P__) atoms with isobutane has been studied by using the dischargeβflow system described previously [1]. The rate constant was measured from determinations of the isobutane concentration in the presence of an excess of O atoms and is given by __k__~1~ = (7.9 Β± 1.4)
## Abstract The absolute rate constant of the reaction of O(^3^__P__) with toluene was measured by the microwave dischargeβfastβflow method to obtain __k__~__T__~ = 10^9.7β2.7/2.303__RT__^ l./moleΒ·sec at 100β375Β°C. This was in good agreement with the rate constant calculated from the combination of
## Abstract The flash photolysisβvacuum ultraviolet kinetic absorption spectroscopy technique has been used to measure the absolute rate constant for the reaction of ground state S(^3^__P__) atoms withnitric oxide,\documentclass{article}\pagestyle{empty}\begin{document}${\rm S}\left({^{\rm 3} P} \r