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The reaction of o-quinone methides with dimethyl sulfoxonium methylide. A simple synthesis of coumarans.

✍ Scribed by Eli Breuer; David Melumad

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
121 KB
Volume
10
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

The reaction of cyclohexyl isocyanide an
The reaction of cyclohexyl isocyanide and dimethyl acetylenedicarboxylate with o- and p-quinones: a novel synthesis of iminolactones
✍ Vijay Nair; A.U Vinod; J.Somarajan Nair; A.R Sreekanth; Nigam P Rath πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 178 KB

The 1:1 intermediate generated by the addition of cyclohexyl isocyanide to dimethyl acetylenedicarboxylate is trapped by quinones to yield iminolactones in good yields.

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