✦ LIBER ✦
The reaction of N,N-dibromobenzenesulfonamide with norbornylene. The occurrence of a hydride shift during an ionic addition to norbornylene
✍ Scribed by A.C. Oehlschlager; L.H. Zalkow
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 241 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The addition of N,N-dibromobenzenesulf'onamide to norbornylene has been found to lead to an extremely rapid exothermic reaction with concomitant precipitation of bcnzenesulfonamide (27%). The benzene soluble portion of the reaction mixture yielded, after chromatography on alumina, three major fractions.
The first fraction (65% based on norbornylene consumed), eluted