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The reaction of N-mono an N,N-disubstituted hydroxylamines with palladium catalyst

โœ Scribed by Shun-Ichi Murahashi; Hitoshi Mitsui; Tomonari Watanabe; Sei-ichi Zenki


Book ID
108381862
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
257 KB
Volume
24
Category
Article
ISSN
0040-4039

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## Abstract The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140โ€‰ยฐC in the presence of 1โ€…mol ppb of the pincer palladium complex [4โ€__tert__โ€butylโ€2,6โ€bis{(3__R__,7a__S__)โ€2โ€phenylhexahydroโ€1__H__โ€pyrrolo[1,2โ€__c__]imidazoleโ€1โ€onโ€3โ€yl}phenyl]chloropalladium to give