The Reaction of N-Bromosuccinimide with 2-Heptene
โ Scribed by Greenwood, Fred L.; Kellert, Morton D.
- Book ID
- 121413458
- Publisher
- American Chemical Society
- Year
- 1953
- Tongue
- English
- Weight
- 314 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract The reaction of 2โmethylenenorbornane with Nโbromosuccinimide produced a mixture of six monobromides in an overall yield of about 60%. By irradiation in the presence of benzoyl peroxide __exo__โ and __endo__โ3โbromoโ2โmethylenenorbornanes, 2โbromomethylnorbornโ2โene, __Z__โ and __E__โ2โ
The reaction of 2-methylnorborn-2-ene with N-bromosuccinimide produced exo-3bromo-2-methylenenorbornane and 2-methyl-3-bromonortricyclene in a 3 : 1 ratio. No 2-bromomethyl-norborn-2-ene was found. Most of the unreacted olefin was found to be isomerized to 2methylenenorbornane. The hydrolysis of 2-