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The reaction of methylborylene with cyclohexene and some other olefinic compounds

✍ Scribed by S.M. Van Der Kerk; J.C. Roos-Venekamp; A.J.M. Van Beijnen; G.J.M. Van Der Kerk

Book ID
108428854
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
668 KB
Volume
2
Category
Article
ISSN
0277-5387

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We wish to report the generation of a hitherto unknown species, viz. methylborylene, CH3B:. The formation of methylborylene was recognized by the products it yielded on reaction with cyclohexene. Methylborylene is generated from methylboron dibromide and a suitable form of potassium, viz. the liquid

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## Abstract Data presented for a range of vulcanized rubbers prepared under different conditions show that while olefinic unsaturation becomes reduced by vulcanization in the proportion of one double bond for each sulphur atom combined with a C~5~H‐unit, the original H/C ratio of 8/5 is not altered