๐”– Bobbio Scriptorium
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The Reaction of Methyl Radicals with n-Butane

โœ Scribed by Gomer, Robert


Book ID
127179482
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
343 KB
Volume
72
Category
Article
ISSN
0002-7863

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The kinetics of reactions involving halogen atom abstraction from haloalkanes by methyl radicals have been studied in the gas phase. Arrhenius parameters for halogen atom transfer were determined relative to those for methyl radical combination: (2) ,,A2(L/rnol . s) E,(kcal/mol) CFC1, CF,CCl, CF,C

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The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi