The Reaction of Methyl Radicals with n-Butane
โ Scribed by Gomer, Robert
- Book ID
- 127179482
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 343 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The kinetics of reactions involving halogen atom abstraction from haloalkanes by methyl radicals have been studied in the gas phase. Arrhenius parameters for halogen atom transfer were determined relative to those for methyl radical combination: (2) ,,A2(L/rnol . s) E,(kcal/mol) CFC1, CF,CCl, CF,C
The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi