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The reaction of methyl radicals with hydrogen peroxide

✍ Scribed by Ulanski, Piotr; Merenyi, Gabor; Lind, Johan; Wagner, Rita; von Sonntag, Clemens

Book ID
121828376
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
110 KB
Volume
4
Category
Article
ISSN
1472-779X

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o