๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The reaction of lithium trialkylalkynylborates with propargyl bromide and iodoacetonitrile. A convenient synthesis of functionally substituted ketones and olefins of defined configuration.

โœ Scribed by Andrew Pelter; Ken J. Gould; Colin R. Harrison


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
197 KB
Volume
16
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Indium-mediated highly regioselective re
โœ Byung-Woo Yoo; Sung-Jae Lee; Kwang-Hyun Choi; Sam-Rok Keum; Jae-Jung Ko; Kyung-I ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 52 KB

Indium-mediated reaction of acyl cyanides 1 with prop-2-ynyl bromides 2 in aqueous media occurs regioselectively to afford either allenic 3 or propargylic ketones 4 depending on the g-substituent of the prop-2-ynyl bromide under the mild conditions.