The Reaction of Lithium Diphenylphosphide and Simple Aryl Halides
β Scribed by Aguiar, Adam M.; Greenberg, Harriet J.; Rubenstein, Kenneth E.
- Book ID
- 127188502
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 411 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Eleven aromatic halides are reduced in very high yields in the presence of LiAlH4 and sonic waves at 35". Recently we have succeeded in accelerating the rates of several reactions using sonic waves.ls3 For example, the Wurtz-type coupling of organic halides, RX, (R = alkyl, aryl, benzyl and benzoyl
The reactions of indene oxide (4a), 5-methoxyindene oxide (4b), 1,2,3,4-tetrahydronaphthalene-1,2-epoxide (5a) and 6-methoxy-1,2,3,4-tetrahydronaphthalene-1,2-epoxide (5b) with lithium halides in the presence of acetic acid (LiX/HOAc) yield mixtures of cis and trans halohydrins. These results are in