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The Reaction of Hydroperoxides with Triphenylphosphine

โœ Scribed by Hiatt, R.; Smythe, R.J.; McColeman, Christine


Book ID
120423043
Publisher
NRC Research Press
Year
1971
Tongue
French
Weight
288 KB
Volume
49
Category
Article
ISSN
0008-4042

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Reaction of polyperoxides with triphenyl
โœ Saraswathyammal Jayanthi; Kaushal Kishore ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 148 KB ๐Ÿ‘ 2 views

The triphenylphosphine deoxygenation of the polyperoxides, poly(styrene peroxide), poly(methyl methacrylate peroxide), and poly( a-methylstyrene peroxide) proceed via the phosphorane intermediates, which in the presence of moisture hydrolyze to give the respective diols. At higher temperatures and u