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THE REACTION OF HYDROGEN SULFIDE WITH SULFOXIDES

โœ Scribed by Mehmet, Y.; Hyne, J. B.

Book ID
121265316
Publisher
Informa UK (Taylor & Francis)
Year
1976
Weight
592 KB
Volume
1
Category
Article
ISSN
0308-664X

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The reversible formation of sulfodichloride intermediates (&,) has been proposed to explain the RlR2SO + 2HCl&lR2SC123 + Ii20 (Eq. 1) 1 s racemization of optically active sulfoxides by hydrogen chloride in organic solvents (Eq. 1). 1,2 Mislow' h8S suggested that the symmetrization of the sulfodic