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The Reaction of Glycidic Esters with Thiourea in Aqueous Sulfuric Acid Solution

✍ Scribed by Durden, John A.; Stansbury, Harry A.; Catlette, William H.

Book ID
120992567
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
449 KB
Volume
81
Category
Article
ISSN
0002-7863

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## Abstract The activation energy parameters for the reaction of PdX (X=Cl^βˆ’^, Br^βˆ’^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas