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The reaction of gas-phase dimethylsilylene with dimethyl ether

✍ Scribed by J.E. Baggott; M.A. Blitz; P.D. Lightfoot

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 459 KB
Volume: 154
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)85365-5

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✦ Synopsis

BieFponentiaI radical concentration-time decay profiles have been obtained in laser flash photolysis/laser absorption studies of the reaction of gas-phase dimethylsilylene, SiMe,, with dimethyl ether. We tentatively ascribe this behaviour to the reversible formation of a lone-pair donor-acceptor complex.

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