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The reaction of ethyleneimine with 5,5-dimethoxytetrachloro-1,3-cyclopentadiene

✍ Scribed by O. G. Nabiev; M. A. Shakhgel'diev; I. I. Chervin; R. G. Kostyanovskii

Book ID: 112442367
Publisher: Springer
Year: 1985
Tongue: English
Weight: 70 KB
Volume: 34
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00947749

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## Abstract The title compound **1** is shown to give, both upon direct irradiation at 254 nm and upon acetophenone‐sensitized photolysis at 300 nm, the __syn__‐vinyl‐pentamethylhousene **5**, which spontaneously rearranges in a [3,3]0sigmatropic process to give the bicyclo[3.2.0]heptadiene skeleto