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The reaction of diiodotriorganophosphorus compounds with dicobalt octacarbonyl; isolation of a new isomeric form of [R3PI] [CoI3(PR3)]

✍ Scribed by Helen P. Lane; Stephen M. Godfrey; Charles A. McAuliffe


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
555 KB
Volume
247
Category
Article
ISSN
0020-1693

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Structural characterization of the tautomeric forms of the zwitterions proposed in the phosphine catalyzed transformations of electron-deficient allenes by utilizing a cyclodiphosphazane with a P-NH-t-Bu group and Ph 2 P(NH-t-Bu) is described. Spontaneous resolution of the products (R and S enantiom