The reaction of bis(p-methoxyphenyl) diazomethane with sulfur dioxide — solvent effect and novel CC bond fission —

Kinetics and mechanism of reaction of tr

Kinetics and mechanism of reaction of trans-(diaqua)(N,N′-ethylene-bis-salicylidenimine) chromium(iii) with sulfur(iv): The labilizing effect of coordinated sulfite

✍ Anadi C. Dash; Achyuta N. Acharya; Prakash Mohanty; Arabinda Das 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 226 KB 👁 2 views

The reaction of trans-[Cr(Salen)(OH 2 ) 2 ] ϩ with aqueous sulfite yields trans-[Cr(Salen)(OH 2 )(OSO 2 9 O)] Ϫ (O-bonded isomer). The rate and activation parameter data for the formation of the sulfito complex are consistent with a mechanism involving rate-limiting addition of SO 2 to the bond. The