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The reaction of bicyclo[2.2.1]Heptadiene with amylsodium a novel cleavage reaction

✍ Scribed by R.A. Finnegan; R.S. McNees

Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
126 KB
Volume
3
Category
Article
ISSN
0040-4039

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✦ Synopsis

WHEN a pentane suspension of amylsodium was allowed to react for 5 hr at room temperature with an equimolar amount of bicyclo[2.2.l]heptadiene (I) and the reaction mixture forced onto an excess of solid C02, a crystalline acid (II) could be isolated in good yield. This acid KBr , AEtoH max 222 mp, "max 1675 cm-l (a, B -unsaturated acid), provided microanalytical data in close agreement with those calculated for the empirical formula C6H602 while its high melting point (204-205', sublimes) (sealed capillary, corrected) suggested that it was at least dibasic, C H 0 .

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