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The reaction of benzeneselenenyl chloride with adamantylideneadamantane

✍ Scribed by Dennis G. Garratt


Book ID
104245734
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
228 KB
Volume
19
Category
Article
ISSN
0040-4039

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A convenient synthesis of 4e-chloroadama
✍ John Bolster; Richard M. Kellogg; Egbert W. Meijer; Hans Wynberg πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 128 KB

We have reported that the reaction of methylsulfenyl halides with ad~antylideneadamantane (1) leads to the formation of a thiiranium salt (x), which in some instances can be isolated.' On treatment with nucleophiles the salt (2a) can undergo either desulfurization or -d~ethylation. ## CR3 x0 Virt