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The Reaction of Aromatic Sulfonyl Azides with Trialkylboranes. An Unusual Synthesis of Aryl, Alkyl Sulfides

โœ Scribed by Ortiz, Margarita; Larson, Gerald L.


Book ID
120484124
Publisher
Taylor and Francis Group
Year
1982
Tongue
English
Weight
174 KB
Volume
12
Category
Article
ISSN
0039-7911

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## Abstract A new PPh~3~โ€catalyzed synthesis of alkyl 2โ€[aryl(tosylimino)methyl]acrylates from propiolate and __N__โ€tosylimine has been developed. Deuteriumโ€labelling experiments show that the reaction mechanism involves several hydrogenโ€transfer processes, which are not the turnoverโ€limiting step