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The reaction of allyl iodide with ketones in the presence of cerium amalgam. An efficient method for the preparation of homoallylic alcohols

✍ Scribed by Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
140 KB
Volume
22
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Cerium chloride-promoted nucleophilic ad
Cerium chloride-promoted nucleophilic addition of grignard reagents to ketones an efficient method for the synthesis of tertiary alcohols
✍ Tsuneo Imamoto; Nobuyuki Takiyama; Kimikazu Nakamura πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 248 KB

In the presence of anhydrous cerium(III1 chloride, Grignard reagents react with ketones to afford addition products in high yields, even though the substrates are susceptible to abnormal reactions with Grignard reagents alone. ## The reaction of Grignard reagents with carbonyl Sympounds is well-k