✦ LIBER ✦
The reaction of allenylsilanes with α,β-unsaturated acylsilanes: new annulation approaches to five and six-membered carbocyclic compounds
✍ Scribed by Rick L. Danheiser; David M. Fink
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 233 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The macation od a,B-un~atukzted acyL&anu with a.Ueny&.Xanu can be directed to phoduce &heh. &ive 0% &ix-mcmbtied ctibacyfic compounds. a,B-Unsaturated acylsilanes are versatile synthetic intermediates, readily participating in Brook reactions, 2 Diels-Alder additions,2 and TiC14 mediated conjugate allylations. 3 In