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The Reaction of 9-Bromoanthracene with Benzenethiolate Anion in Tetraglyme: Evidence against a competing electron-transfer mechanism

✍ Scribed by Charles D. Baumgarner; Alyssa H. Malen; Stephen D. Pastor; M. Ali NabiRahni


Publisher
John Wiley and Sons
Year
1992
Tongue
German
Weight
432 KB
Volume
75
Category
Article
ISSN
0018-019X

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✦ Synopsis


For the direct reduction of a-haloketones with thiols, see [9d]; for a recent study, see [9e]


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The reaction of cyclopropanes like 2,3,4-triphenyl-endo-tricyclo[3.2.1.02'0]octane (la) with base is initiated by proton and not by ele$trov transfer. The facile disrotatory cyclopropyl anion ring opening reaction of 2JR2=CN, M =Ll ) at -75Β°C does not occur synchronously. 2,3,4-Triphenyl-endo-tricyc