The reaction of 6,8-disubstituted E,E-germacra-1(10),4-diene 4-epoxides with oxyphilic reagents
โ Scribed by Giovanni Appendino; Jasmin Jakupovic; Giancarlo Cravotto; Maique Biavatti-Weber
- Book ID
- 104207680
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 759 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4020
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โฆ Synopsis
Treatment of a group of closely related 1.4-germacradicuc-4.-epoxides with various ox3'philic reagents gave a remarkable arra) of sesquiterpenoid structures, effeclively "'amplifying" the skeletal diversity of the starling library.
๐ SIMILAR VOLUMES
We had previously demonstrated the utility of N-vinylpyridinium tetrafluoroborate salts as novel electrophilic coupling partners in Pd(0)-catalyzed Suzuki cross-coupling reactions with aryl and vinyl boronic acids. We now report that these crystalline, air-stable, and non-hygroscopic salts are also