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The reaction of 3-alkene-1-ols with aldehydes: A synthesis of (±)-cis-2-(2′methyl-1′-propenyl)-4-methyltetrahydropyran

✍ Scribed by J.H.P. Tyman; B.J. Willis


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
127 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis


The acid-oatalysed interaction of 2-methyl-1-psntene-4-cl with a oarbcayl compamd (RR'CO) was believed' to yield the pyran (I) by ney of the pyraaol


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3-Zircons-l-cyclopentenes and zirconacyclopentanes react with aidehydes at or below 25 OC to give the correspondmg carbonyl addition pmducts. i.e., 'I-membered oxazirconacycles, which can be readily converted to the corresponding alcohols via protonolysis and S-iodoalcohols via iodinolysis; the latt