The reaction of 2-picolyllithium with schiff bases
โ Scribed by Richard F. Shuman; E. D. Amstutz
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 732 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0165-0513
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Although enamines are known to be excellent addends in many Michael type reactions, the reaction of enamines with Schiff bases has hitherto never been found in the literatures. We now would like to report the reaction and its stereochemical consequence. Reaction of 1-morpholino-l-cyclohexene (Ia) o
Acetophenolle anilreactedwith cna mole ofPCCl53DM, inIMP2, and afforded after treawt rith perohlorio acid, the salt Ia, m.p. 160ยฐ, which upcm azlrrlina i&ydrol,ymir,gmva the x-for@m"ldnrr IIa3,B.p.1300. Tbs mtxuoture of IIaru inferred frcm ita IR (1660 or?) and lDllIL rpectra (CDC13)r ai@alm at 4.5