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The Reaction of 1,2:3,4-Diepoxy-2,3-dimethylbutane with Nucleophiles

✍ Scribed by Frédéric Farkas; Thomas Wellauer; Thomas Esser; Urs Séquin

Publisher
John Wiley and Sons
Year
1991
Tongue
German
Weight
658 KB
Volume
74
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

To find out whether the 1,4‐addition to 1,2:3,4‐diepoxides, which so far has been observed only once, is of a more general character, we investigated the reaction of a variety of O‐, C‐, N‐, and S‐nucleophiles with the model compound 1,2:3,4‐diepoxy‐2,3‐dimethylbutane (Scheme 4). In several cases, 1,4‐addition products could, indeed, be observed besides the expected 1,2‐adducts (Table).

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