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The Reaction of 1, 2-Disubstituted-3-Benzylglycerols and Trimethylsilyl Iodide (TMSI). Improved Method for the Preparation of 1, 2-Dialkylglycerols

โœ Scribed by Berk, Howard C.; Zwickelmaier, Kurt E.; Franz, John E.


Book ID
118150731
Publisher
Taylor and Francis Group
Year
1985
Tongue
English
Weight
127 KB
Volume
15
Category
Article
ISSN
0039-7911

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Simple procedures for the preparation of
โœ Narayan G Bhat; Claudia P Aguirre ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 67 KB

Two simple procedures for obtaining (Z)-2-(1-trimethylsilyl-1-alkenyl)-1,3,2-dioxaborinanes based on 1-trimethylsilyl-1-alkynes are described. In the first procedure, 1-trimethylsilyl-1-alkynes are hydroborated with diisopinocampheylborane to provide the corresponding (Z)-2-(trimethylsilyl-1-alkenyl