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The reaction of 0,0-dialkyl dithiophosphoric acid—VI : Reaction of carbostyril with 0,0-dialkyl or 0,0-diphenyl dithiophosphoric acid

✍ Scribed by A. Nakanishi; S. Oae

Book ID
103398395
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
235 KB
Volume
29
Category
Article
ISSN
0040-4020

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A new method for the synthesis of S-alkyl methylthiophosphonic acid derivatives is reported. The chlorination of 0,O-dialkyl methylthiophosphonates 8 with phosphorus oxychloride proceeds with isomerization of the P = S to the P-S bond to give S-alkyl methylthiophosphonochloridates 9, which react fur