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The reaction energies of ethylene, CO, and N2with proton, hydrogen atom, and hydride ion

✍ Scribed by Markov, A. A.; Sharifullina, G. F.; Dolin, S. P.; Moiseeva, N. I.; Gekhman, A. E.; Moiseev, I. I.


Book ID
118809832
Publisher
Springer
Year
2011
Tongue
English
Weight
301 KB
Volume
60
Category
Article
ISSN
1573-9171

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Ethylenediamine (en) solutions of [P 7 M(CO) 3 ] 3Β± (M = Cr, W) react with weak acids to give [HP 7 M(CO) 3 ] 2Β± ions where M = Cr (4 a) and W (4 b) in high yields. Competition studies with known acids revealed a pK a range for 4 b in DMSO of 17.9 to 22.6. The [P 7 M(CO) 3 ] 3Β± complexes also react