The reaction energies of ethylene, CO, and N2with proton, hydrogen atom, and hydride ion
β Scribed by Markov, A. A.; Sharifullina, G. F.; Dolin, S. P.; Moiseeva, N. I.; Gekhman, A. E.; Moiseev, I. I.
- Book ID
- 118809832
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 301 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1573-9171
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The bimolecular reaction of 'CH20H2+ with a variety of neutral molecules in the gas phase were studied by Fourier transform ion cyclotron resonance experiments. The distonic ion is found to be considerably more acidic than protonated methanol; bracketing experiments provide a value of 695 8 kJ mol-'
Ethylenediamine (en) solutions of [P 7 M(CO) 3 ] 3Β± (M = Cr, W) react with weak acids to give [HP 7 M(CO) 3 ] 2Β± ions where M = Cr (4 a) and W (4 b) in high yields. Competition studies with known acids revealed a pK a range for 4 b in DMSO of 17.9 to 22.6. The [P 7 M(CO) 3 ] 3Β± complexes also react