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The reaction between trans-2-alkylaminocycloalkanols and formaldehyde

✍ Scribed by Peter M. R. Barkworth; Trevor A. Crabb

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
455 KB
Volume
17
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

trans‐2‐Alkylaminocyclohexanols and trans‐2‐alkylaminocycloheptanols condense with formaldehyde to give perhydrocycloalkano[d][1,3]oxazoles, whereas trans‐2‐alkylaminocyclopentanols give rise to perhydrocyclopentano[f][1,3,5]dioxazepines. The two types of ring systems are characterized by differing proton‐proton geminal coupling constants and ^13^C NMR parameters.

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