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The Reaction between Metal Carbonyls and Amines. II. Iron Carbonyl with Pyrrolidine. Initial Stages of the Reaction 1-3

โœ Scribed by Edgell, Walter F.; Bulkin, Bernard J.

Book ID
127157356
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
613 KB
Volume
88
Category
Article
ISSN
0002-7863

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
โœ J.E. Pardue; G.R. Dobson ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo