The ratio NO2NO in fuel-lean flames
β Scribed by C.P. Fenimore
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 347 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0010-2180
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β¦ Synopsis
In fuel-lean premixed flames at atmospheric pressure, containing about 100 ppm of nitrogen oxides, the ratio NO2/NO is large in the primary reaction zone. The ratio decreases in the post-flame gas where super-equilibrium concentrations of O, OH, etc., also decrease. During the decrease, the equilibrium
is approximately satisfied, and a possible mechanism to maintain (2) can be suggested. The equilibrium fails in cooler gas: At around 1200 Β°K or less, NO2/NO is quenched and no longer remains balanced with the concentration of O atoms.
π SIMILAR VOLUMES
We observed optical saturation curves of the Na(SP) level in cool (T -1700K) premixed laminar H2-O2-Ar flames at 1 atm and in a wide range of fuel/oxidant ratios below as well as above stoichiometry. A pulsed dye laser (pulse duration of 1.2 /~s) was tuned at the upper doublet component. For this re