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The Rates of Condensation of Piperidine with 1-Chloro-2,4-dinitrobenzene in Various Solvents

✍ Scribed by Bunnett, J. F.; Morath, R. J.

Book ID: 126804236
Publisher: American Chemical Society
Year: 1955
Tongue: English
Weight: 141 KB
Volume: 77
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01624a063

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## Abstract The second‐order rate coefficients for aromatic nucleophilic substitution reaction between 1‐chloro‐2,4‐dinitrobenzene and aniline have been measured in aqueous solutions of ethanol and methanol at 25°C. The plots of rate constants versus mole fraction of water show a maximum in all‐aqu