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The Rates and Mechanisms of Substitution of Square-Planar Complexes of Ni (II), Pd(II), AND Pt(II) Containing Bidentate Sulphur Ligands in Water and Methanol

โœ Scribed by M. J. Hynes and Patricia F. Brannick


Book ID
125274344
Publisher
Royal Irish Academy
Year
1977
Weight
973 KB
Volume
77
Category
Article
ISSN
0035-8983

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โœ Udo Beckmann; Gerhard Hรคgele; Walter Frank ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 506 KB

## Abstract Nickel(II) complexes comprising electronically delocalised __N__,__O__โ€chelating ligands are active catalysts in the copolymerisation of carbon monoxide and ethene. Elucidating the mechanism of catalysis presupposes the basic understanding of the intramolecular flexibility of such trans