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The rate of oxygen exchange between ReO4− and H2O

✍ Scribed by R.K. Murmann


Book ID
118904511
Publisher
Elsevier Science
Year
1961
Weight
333 KB
Volume
18
Category
Article
ISSN
0022-1902

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Studies on the rate of isotopic oxygen e
✍ Fred F. Kashani; R. Kent Murmann 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 479 KB 👁 1 views

The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex