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The rate of aquation of trans-chloro-thioreabis (ethylenediamine) cobalt (III) cation and analogous substituted thiourea complexes

✍ Scribed by W.A. Baker Jr.; F.M. Gaesser


Book ID
118904941
Publisher
Elsevier Science
Year
1963
Weight
333 KB
Volume
25
Category
Article
ISSN
0022-1902

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The kinetics of aquation and racemizatio
✍ D. R. Fenemor; D. A. House πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 482 KB

Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80Β°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo