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The ram perturbation theory and the hard dumbbell fluid

โœ Scribed by Ivo Nezbeda; William R. Smith

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
266 KB
Volume
64
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

THE RAM PERTURBATION THEORY AND THE HARb DUMBBELL FLUID Ivo NEZBEDA Wlhm R. SMITH The RAM perturbation theom is ekxluated in the use of the hard dumbbell fluid and compared with computer simuhtion rcsuIts. The zeroth-order theory lieIds good agreement nith the centres pair correhtion functiongooo(r) even up to Iage dumbbell sphere sep;lr;ttions. thus sirowing that the basic idea of the theory is sound. Some possible reasons for the failure of 3 rehted perturbation theory are discussed.

๐Ÿ“œ SIMILAR VOLUMES

The RAM perturbation theory for inhomoge
The RAM perturbation theory for inhomogeneous molecular fluids: Hard dumbbells at a hard wall
โœ William R. Smith; Ivo Nezbeda; M.R. Reddy ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 315 KB

It is shown that the RAM theory of homogeneous molecular fluids czm be successfully exrended aiso lo mhomogcncous fluids. The theory has been applied to caIcula!e density profdes of 3 hard dumbbell fluid a? 3 hard ~rrucrurcIc~~ ~~11.

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perturbed hard chain theory based equation of state is investigated in view of its application to supercritical fluid extraction process calculations. This investigation is an extension of a previous paper in which attention was given to pure component properties and in which a method was proposed f

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where p is the nwnber density; the hard core condirion h(r)= -I\\_ T cl\\_ (3) Considerable study h-as been made [3,-l] of the case in which cqs\\_ (1) tc (3) are regarded xs the mean spherical appro-ximation (MSA) [5] conditions for a fluid of hard spheres with attractive Yukawa interaction\\_ That