THE RADIOLYTIC SYNTHESIS OF THE cis- AND trans-ISOMERS OF 1,2-DICHLOROETHYLENE OXIDE
β Scribed by Futrell, Jean H.; Newton, Amos S.
- Book ID
- 126402207
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 282 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Cis and trans 1,2dichloroethylene react with LiPPha [l] and LiAsPha [2, 31 stereospecifically to form the corresponding vinylic diphosphines and diarsines in high yield. However cis 1,2dichloroethylene and NaAsMea produce 1,2-bis(dimethylarsino)ethylene, MeaAsCH = CHAsMea, in approximately 30% with
The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22Β°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma