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The radical ions from bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphaallene. A multi-disciplinary approach and a reassessment

✍ Scribed by Alberti, Angelo; Benaglia, Massimo; D’Angelantonio, Mila; Emmi, Salvatore S.; Guerra, Maurizio; Hudson, Andrew; Macciantelli, Dante; Paolucci, Francesco; Roffia, Sergio


Book ID
119960447
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
311 KB
Volume
2
Category
Article
ISSN
1472-779X

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## Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.