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The radiation-induced graft copolymerization of 4-vinyl pyridine and acrylamide to nylon 6.6

✍ Scribed by Sykes, J. A. W. ;Thomas, J. K.


Book ID
104531994
Publisher
John Wiley and Sons
Year
1961
Weight
471 KB
Volume
55
Category
Article
ISSN
0022-3832

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✦ Synopsis


Abstract

Appreciable quantities of 4‐vinyl pyridine and acrylamide have been grafted to nylon 6.6 by decomposing in their presence the peroxides and hydroperoxides formed on irradiating the polymer in air with γ‐rays. The kinetics of the grafting process is interpreted in terms of a diffusion of the monomer into the nylon. The enhanced dyeing of the amine grafts and the lowering of the surface resistance of the graft by quaternization with dimethylsulfate are also reported.


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Grafting of acrylamide (AAm) onto poly(vinyl chloride) (PVC) Ðlms using gamma radiation has been carried out. The e †ects of di †erent parameters on the graft yield have been investigated. These parameters include radiation dose, monomer concentration, solvent composition, types of inhibitors and ac