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The Question of Aromaticity in Open-Shell Cations and Anions as Ion-Radical Offsprings of Polycyclic Aromatic and Antiaromatic Hydrocarbons

✍ Scribed by Rosokha, Sergiy V.; Kochi, Jay K.

Book ID: 126394130
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 204 KB
Volume: 71
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo061695a

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## Abstract Contact ion pairs of aromatic radical anions, with a crown ether complex of potassium as cation in a neat aromatic hydrocarbon, can be obtained by reducing the aromatic hydrocarbon in which a small amount of crown ether is dissolved. The unpaired electron stays attached to one aromatic