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The question of a pressure effect in the reaction OH + CO at room temperature

✍ Scribed by Ralph Overend; George Paraskevopoulos

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 306 KB
Volume: 49
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80452-1

No coin nor oath required. For personal study only.

✦ Synopsis

Absolute rate constants for the rcaction of OH with CO were determined at 296 + 2 K, with 50 torr of Hc and 0-350 tOrr Of SF6. Thc rate constant was found to change from = 1.0 x lol1 to = 1.9 x lol1 cm3 mol-l s-' depcndmo on thc pressure and nature of the third body M, in agreement with our earlicr results and with the threc studies by Heicklcn, Co, Calvert, and their co-workers. However, it is not possible, at present, to attribute thc effect with certamty to any particular cause.

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