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The Quantum Efficiency of the Mercury Sensitized Photochemical Decomposition of Hydrogen

✍ Scribed by Thomas, Lloyd B.; Gwinn, Wm. D.

Book ID: 126302329
Publisher: American Chemical Society
Year: 1948
Tongue: English
Weight: 754 KB
Volume: 70
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01188a009

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Although the homogeneous decompositiun of H102 vapor is a nonchain process. a chain reaction occurs in the prescncc UT Ij2. as a result of the reaction OH + H, = H,O + H f I). followed by H + H,lO, = Hz0 + OH (II). At low concentrations chain tcrminotior: results from the reaction 01-I + H202 = HI0