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The quadrupole coupling tensor of methyl amine

✍ Scribed by Marek Krȩglewski; Wolfgang Stahl; Jens-Uwe Grabow; Georges Wlodarczak


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
320 KB
Volume
196
Category
Article
ISSN
0009-2614

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✦ Synopsis


Accurate quadrupole coupling constants have been determined from the hyperline splittings of the JKr=20B,+ I ,Bz and 2,,E, + 1+ 1 ,E, -1 transitions (f being a symmetry label) in the ground state of methyl amine, CH,NH,, recorded with a microwave Fourier transform molecular beam spectrometer. These constants, combined with the data for CD3NH2 and CD,ND2, have been used for the calculation of the diagonal quadrupole coupling tensor.


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The \(b\)-type rotational spectrum of \({ }^{28} \mathrm{SiH}_{2}{ }^{35} \mathrm{Cl}_{2}\) has been remeasured in the frequency region 10.3-15.7 GHz \((J=1-10)\) using a microwave Fourier transform (MWFT) cavity spectrometer. The MWFT technique has permitted resolution of the complex hyperfine patt