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The Pyrolysis of Sulfites. III. Methyl Alkyl Sulfites. A New Method for the Preparation of Olefins

โœ Scribed by Berti, Giancarlo


Book ID
120479876
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
958 KB
Volume
76
Category
Article
ISSN
0002-7863

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A new method for the preparation of olef
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A novel method is reported for the transformation of vicinal diols to olefins. This methodology consists in the conversion of iodothiocarbonates such as 16 to olefin 17 with phenyl lithium in excellent yield. Compounds 7 and 12 were prepared by this methodology in order to determine if they would be